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Does soap repel water?



The Next CEO of Stack OverflowDoes tea stay hotter with the milk in it?can Superconductivity be used to repel water?Why does the water rise?Water Level and Pipe WidthsThe Soda Can and air pressure experimentWhy does a pitcher with lemon juice have foam, while one with pure water does not?Why does water get significantly colder while falling through the air?Can a hose filled with water go up if there is not a lot of pressure?How does sawdust selectively absorb water?Why soap bubbles are made of soap?










13












$begingroup$


Yesterday when I was taking my bath, I scratched my soap bar a bit and threw that bit on the shower area floor. There was a little amount of water on the floor tile where that soap bit fell. To my surprise, I noticed that the the water around that soap bit had moved away surrounding it. I'm clueless why did it happen. I also tried to reproduce the results and every time the water would surround that soap bit without touching it. The water around would sort of encircle the soap bit. Is this because of soap micelles? I know that the hydrophilic head of the micelles always point outwards so shouldn't the water be attracted towards the soap bit? Rather it seems that soap and water repel each other. Could you please explain why does it happen? You could also repeat this experiment in your house.



EDIT $1:$ I repeated the experiment with the tiles in my drawing room which are very smooth and nothing of that sort happened. I think only the ("little") rough tiles (which are in my bathroom) can be used to see "soap repel water". Moreover the tiles in my drawing room also don't spread water when a bit of water is thrown on one.










share|cite|improve this question











$endgroup$











  • $begingroup$
    What's your shower floor made of? Ceramic tiles? Do small amounts of water spread out on it, or does it form into beads (droplets)? Consider what soap does to the surface tension.
    $endgroup$
    – PM 2Ring
    yesterday










  • $begingroup$
    @PM 2Ring water spreads and doesn't form into droplets
    $endgroup$
    – user8718165
    yesterday















13












$begingroup$


Yesterday when I was taking my bath, I scratched my soap bar a bit and threw that bit on the shower area floor. There was a little amount of water on the floor tile where that soap bit fell. To my surprise, I noticed that the the water around that soap bit had moved away surrounding it. I'm clueless why did it happen. I also tried to reproduce the results and every time the water would surround that soap bit without touching it. The water around would sort of encircle the soap bit. Is this because of soap micelles? I know that the hydrophilic head of the micelles always point outwards so shouldn't the water be attracted towards the soap bit? Rather it seems that soap and water repel each other. Could you please explain why does it happen? You could also repeat this experiment in your house.



EDIT $1:$ I repeated the experiment with the tiles in my drawing room which are very smooth and nothing of that sort happened. I think only the ("little") rough tiles (which are in my bathroom) can be used to see "soap repel water". Moreover the tiles in my drawing room also don't spread water when a bit of water is thrown on one.










share|cite|improve this question











$endgroup$











  • $begingroup$
    What's your shower floor made of? Ceramic tiles? Do small amounts of water spread out on it, or does it form into beads (droplets)? Consider what soap does to the surface tension.
    $endgroup$
    – PM 2Ring
    yesterday










  • $begingroup$
    @PM 2Ring water spreads and doesn't form into droplets
    $endgroup$
    – user8718165
    yesterday













13












13








13


0



$begingroup$


Yesterday when I was taking my bath, I scratched my soap bar a bit and threw that bit on the shower area floor. There was a little amount of water on the floor tile where that soap bit fell. To my surprise, I noticed that the the water around that soap bit had moved away surrounding it. I'm clueless why did it happen. I also tried to reproduce the results and every time the water would surround that soap bit without touching it. The water around would sort of encircle the soap bit. Is this because of soap micelles? I know that the hydrophilic head of the micelles always point outwards so shouldn't the water be attracted towards the soap bit? Rather it seems that soap and water repel each other. Could you please explain why does it happen? You could also repeat this experiment in your house.



EDIT $1:$ I repeated the experiment with the tiles in my drawing room which are very smooth and nothing of that sort happened. I think only the ("little") rough tiles (which are in my bathroom) can be used to see "soap repel water". Moreover the tiles in my drawing room also don't spread water when a bit of water is thrown on one.










share|cite|improve this question











$endgroup$




Yesterday when I was taking my bath, I scratched my soap bar a bit and threw that bit on the shower area floor. There was a little amount of water on the floor tile where that soap bit fell. To my surprise, I noticed that the the water around that soap bit had moved away surrounding it. I'm clueless why did it happen. I also tried to reproduce the results and every time the water would surround that soap bit without touching it. The water around would sort of encircle the soap bit. Is this because of soap micelles? I know that the hydrophilic head of the micelles always point outwards so shouldn't the water be attracted towards the soap bit? Rather it seems that soap and water repel each other. Could you please explain why does it happen? You could also repeat this experiment in your house.



EDIT $1:$ I repeated the experiment with the tiles in my drawing room which are very smooth and nothing of that sort happened. I think only the ("little") rough tiles (which are in my bathroom) can be used to see "soap repel water". Moreover the tiles in my drawing room also don't spread water when a bit of water is thrown on one.







everyday-life water physical-chemistry home-experiment






share|cite|improve this question















share|cite|improve this question













share|cite|improve this question




share|cite|improve this question








edited yesterday







user8718165

















asked yesterday









user8718165user8718165

33014




33014











  • $begingroup$
    What's your shower floor made of? Ceramic tiles? Do small amounts of water spread out on it, or does it form into beads (droplets)? Consider what soap does to the surface tension.
    $endgroup$
    – PM 2Ring
    yesterday










  • $begingroup$
    @PM 2Ring water spreads and doesn't form into droplets
    $endgroup$
    – user8718165
    yesterday
















  • $begingroup$
    What's your shower floor made of? Ceramic tiles? Do small amounts of water spread out on it, or does it form into beads (droplets)? Consider what soap does to the surface tension.
    $endgroup$
    – PM 2Ring
    yesterday










  • $begingroup$
    @PM 2Ring water spreads and doesn't form into droplets
    $endgroup$
    – user8718165
    yesterday















$begingroup$
What's your shower floor made of? Ceramic tiles? Do small amounts of water spread out on it, or does it form into beads (droplets)? Consider what soap does to the surface tension.
$endgroup$
– PM 2Ring
yesterday




$begingroup$
What's your shower floor made of? Ceramic tiles? Do small amounts of water spread out on it, or does it form into beads (droplets)? Consider what soap does to the surface tension.
$endgroup$
– PM 2Ring
yesterday












$begingroup$
@PM 2Ring water spreads and doesn't form into droplets
$endgroup$
– user8718165
yesterday




$begingroup$
@PM 2Ring water spreads and doesn't form into droplets
$endgroup$
– user8718165
yesterday










1 Answer
1






active

oldest

votes


















14












$begingroup$

tl;dr- When the soap touched the water, part of it dissolved, reducing the local surface tension. The water moved away from the soap since that's where the surface tension was lowest, before the surface tension equaled out as the soap particles spread throughout the water.




I'd guess that this is the Marangoni effect:




Since a liquid with a high surface tension pulls more strongly on the surrounding liquid than one with a low surface tension, the presence of a gradient in surface tension will naturally cause the liquid to flow away from regions of low surface tension.




In this case, the water is moving away from the soap because that's the direction of increasing surface tension.



Why? Because a little bit of the soap dissolved upon contact, and soap, as a surfactant, reduces surface tension.



Here's a neat demo of it:




  • "A BOAT POWERED BY SOAP?!".

And a corresponding YouTube clip:




  • "Seven Science Experiments with Surface Tension" @1:05.

In this demo, a little paper boat is sitting in a bit of water. The experimenter touches the water near the boat with a bit of soap, reducing the local surface tension, driving the boat in the opposite direction.



You're probably observing much the same thing, just without the little boat.




When the Marangoni effect causes a fluid (like the water) to move along a surface (like the floor) due to a concentration gradient (like the dissolved soap's), it's called "diffusioosmosis":




Diffusioosmosis, also referred to as capillary osmosis, is flow of a solution relative to a fixed wall or pore surface, where the flow is driven by a concentration gradient in the solution.







share|cite|improve this answer











$endgroup$












  • $begingroup$
    thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
    $endgroup$
    – Nat
    yesterday










  • $begingroup$
    Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
    $endgroup$
    – Nat
    yesterday







  • 3




    $begingroup$
    I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
    $endgroup$
    – Marc.2377
    yesterday












Your Answer





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1 Answer
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active

oldest

votes








1 Answer
1






active

oldest

votes









active

oldest

votes






active

oldest

votes









14












$begingroup$

tl;dr- When the soap touched the water, part of it dissolved, reducing the local surface tension. The water moved away from the soap since that's where the surface tension was lowest, before the surface tension equaled out as the soap particles spread throughout the water.




I'd guess that this is the Marangoni effect:




Since a liquid with a high surface tension pulls more strongly on the surrounding liquid than one with a low surface tension, the presence of a gradient in surface tension will naturally cause the liquid to flow away from regions of low surface tension.




In this case, the water is moving away from the soap because that's the direction of increasing surface tension.



Why? Because a little bit of the soap dissolved upon contact, and soap, as a surfactant, reduces surface tension.



Here's a neat demo of it:




  • "A BOAT POWERED BY SOAP?!".

And a corresponding YouTube clip:




  • "Seven Science Experiments with Surface Tension" @1:05.

In this demo, a little paper boat is sitting in a bit of water. The experimenter touches the water near the boat with a bit of soap, reducing the local surface tension, driving the boat in the opposite direction.



You're probably observing much the same thing, just without the little boat.




When the Marangoni effect causes a fluid (like the water) to move along a surface (like the floor) due to a concentration gradient (like the dissolved soap's), it's called "diffusioosmosis":




Diffusioosmosis, also referred to as capillary osmosis, is flow of a solution relative to a fixed wall or pore surface, where the flow is driven by a concentration gradient in the solution.







share|cite|improve this answer











$endgroup$












  • $begingroup$
    thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
    $endgroup$
    – Nat
    yesterday










  • $begingroup$
    Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
    $endgroup$
    – Nat
    yesterday







  • 3




    $begingroup$
    I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
    $endgroup$
    – Marc.2377
    yesterday
















14












$begingroup$

tl;dr- When the soap touched the water, part of it dissolved, reducing the local surface tension. The water moved away from the soap since that's where the surface tension was lowest, before the surface tension equaled out as the soap particles spread throughout the water.




I'd guess that this is the Marangoni effect:




Since a liquid with a high surface tension pulls more strongly on the surrounding liquid than one with a low surface tension, the presence of a gradient in surface tension will naturally cause the liquid to flow away from regions of low surface tension.




In this case, the water is moving away from the soap because that's the direction of increasing surface tension.



Why? Because a little bit of the soap dissolved upon contact, and soap, as a surfactant, reduces surface tension.



Here's a neat demo of it:




  • "A BOAT POWERED BY SOAP?!".

And a corresponding YouTube clip:




  • "Seven Science Experiments with Surface Tension" @1:05.

In this demo, a little paper boat is sitting in a bit of water. The experimenter touches the water near the boat with a bit of soap, reducing the local surface tension, driving the boat in the opposite direction.



You're probably observing much the same thing, just without the little boat.




When the Marangoni effect causes a fluid (like the water) to move along a surface (like the floor) due to a concentration gradient (like the dissolved soap's), it's called "diffusioosmosis":




Diffusioosmosis, also referred to as capillary osmosis, is flow of a solution relative to a fixed wall or pore surface, where the flow is driven by a concentration gradient in the solution.







share|cite|improve this answer











$endgroup$












  • $begingroup$
    thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
    $endgroup$
    – Nat
    yesterday










  • $begingroup$
    Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
    $endgroup$
    – Nat
    yesterday







  • 3




    $begingroup$
    I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
    $endgroup$
    – Marc.2377
    yesterday














14












14








14





$begingroup$

tl;dr- When the soap touched the water, part of it dissolved, reducing the local surface tension. The water moved away from the soap since that's where the surface tension was lowest, before the surface tension equaled out as the soap particles spread throughout the water.




I'd guess that this is the Marangoni effect:




Since a liquid with a high surface tension pulls more strongly on the surrounding liquid than one with a low surface tension, the presence of a gradient in surface tension will naturally cause the liquid to flow away from regions of low surface tension.




In this case, the water is moving away from the soap because that's the direction of increasing surface tension.



Why? Because a little bit of the soap dissolved upon contact, and soap, as a surfactant, reduces surface tension.



Here's a neat demo of it:




  • "A BOAT POWERED BY SOAP?!".

And a corresponding YouTube clip:




  • "Seven Science Experiments with Surface Tension" @1:05.

In this demo, a little paper boat is sitting in a bit of water. The experimenter touches the water near the boat with a bit of soap, reducing the local surface tension, driving the boat in the opposite direction.



You're probably observing much the same thing, just without the little boat.




When the Marangoni effect causes a fluid (like the water) to move along a surface (like the floor) due to a concentration gradient (like the dissolved soap's), it's called "diffusioosmosis":




Diffusioosmosis, also referred to as capillary osmosis, is flow of a solution relative to a fixed wall or pore surface, where the flow is driven by a concentration gradient in the solution.







share|cite|improve this answer











$endgroup$



tl;dr- When the soap touched the water, part of it dissolved, reducing the local surface tension. The water moved away from the soap since that's where the surface tension was lowest, before the surface tension equaled out as the soap particles spread throughout the water.




I'd guess that this is the Marangoni effect:




Since a liquid with a high surface tension pulls more strongly on the surrounding liquid than one with a low surface tension, the presence of a gradient in surface tension will naturally cause the liquid to flow away from regions of low surface tension.




In this case, the water is moving away from the soap because that's the direction of increasing surface tension.



Why? Because a little bit of the soap dissolved upon contact, and soap, as a surfactant, reduces surface tension.



Here's a neat demo of it:




  • "A BOAT POWERED BY SOAP?!".

And a corresponding YouTube clip:




  • "Seven Science Experiments with Surface Tension" @1:05.

In this demo, a little paper boat is sitting in a bit of water. The experimenter touches the water near the boat with a bit of soap, reducing the local surface tension, driving the boat in the opposite direction.



You're probably observing much the same thing, just without the little boat.




When the Marangoni effect causes a fluid (like the water) to move along a surface (like the floor) due to a concentration gradient (like the dissolved soap's), it's called "diffusioosmosis":




Diffusioosmosis, also referred to as capillary osmosis, is flow of a solution relative to a fixed wall or pore surface, where the flow is driven by a concentration gradient in the solution.








share|cite|improve this answer














share|cite|improve this answer



share|cite|improve this answer








edited yesterday

























answered yesterday









NatNat

3,66341932




3,66341932











  • $begingroup$
    thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
    $endgroup$
    – Nat
    yesterday










  • $begingroup$
    Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
    $endgroup$
    – Nat
    yesterday







  • 3




    $begingroup$
    I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
    $endgroup$
    – Marc.2377
    yesterday

















  • $begingroup$
    thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
    $endgroup$
    – Nat
    yesterday










  • $begingroup$
    Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
    $endgroup$
    – user8718165
    yesterday











  • $begingroup$
    @user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
    $endgroup$
    – Nat
    yesterday







  • 3




    $begingroup$
    I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
    $endgroup$
    – Marc.2377
    yesterday
















$begingroup$
thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
$endgroup$
– user8718165
yesterday





$begingroup$
thanks for the answer but is the effect tile dependent? I couldn't reproduce the results on wood or the smooth tiles which I have got. Moreover unlike my bathroom tiles, those tiles also don't spread water when it falls on them.
$endgroup$
– user8718165
yesterday













$begingroup$
@user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
$endgroup$
– Nat
yesterday




$begingroup$
@user8718165 You're inducing a dynamic effect, where there's a temporary force due to a temporary difference in surface tension. I'd expect it to be most observable on a very hydrophobic surface, on which the water is beaded up, since the water's own forces would dominate there, maximizing the effect. On a very hydrophillic surface, it'd seem like the water would tend to interact less with itself, and be more attached to the surface itself, such that this effect would probably be less observable.
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– Nat
yesterday












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Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
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– user8718165
yesterday





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Is the tile where water spreads out rather than getting beaded up a hydrophobic surface and the tile where water doesn't spread out at all a hydrophilic surface?
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– user8718165
yesterday













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@user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
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– Nat
yesterday





$begingroup$
@user8718165 If the water spreads out rather than beading, that'd sound more hydrophillic. Admittedly I'm half-asleep right now, but it sounds a bit weird to me that your bathroom tiles would be more hydrophillic than other tiles in your house. I mean, your bathroom is like the one place where it's most important for surfaces to be water-repelling. They even sell bathroom products specifically for this purpose (random example on Amazon.com).
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– Nat
yesterday





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I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
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– Marc.2377
yesterday





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I remember doing a magic trick as a kid, sprinkling black pepper on a bowl of water and touching it with a tiny amount of soap at the fingertip. The black pepper immediately repels. Now I know why!
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– Marc.2377
yesterday


















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