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Can Rydberg constant be in joules?
Understanding Moseley’s law from the Rydberg-type equation?Finding orbit radius using the Bohr model and Rydberg equationUnits in modified Arrhenius equation?Molar heat of reaction for water in a neutralization reactionReaction rate constant conversionEffects of Changing Avogadro's ConstantCalculate pressure equilibrium constant from concentration equilibrium constantis rydberg constant and rydberg unit are same?Conversion from a PPB value to µg/m3 of IsobutyleneBarron states that 4.18×10⁸ joules equal 1 kcal, is this correct?
.everyoneloves__top-leaderboard:empty,.everyoneloves__mid-leaderboard:empty,.everyoneloves__bot-mid-leaderboard:empty margin-bottom:0;
$begingroup$
In my textbook (Chemistry Part - I for Class XI published by NCERT), there is an equation for the energy of an electron in an energy state: $$E_n = -R_mathrm Hleft(frac1n^2right)$$ and there is a paragraph below it with the following text:
where $R_mathrm H$ is called Rydberg constant and its value is $2.18times10^-18 textJ$.
There is another section with the expression for the wavenumber ($overlinenu$):
$$overlinenu=109,677 left(frac1n_1^2 - frac1n_2^2right) textcm^-1$$
with a paragraph with the following text:
The value $109,677 spacetextcm^-1$ is called the Rydberg constant for hydrogen.
I checked online and found that in most (all) websites (incl. Wikipedia), the value of Rydberg constant is $109,677 spacetextcm^-1$. But when I searched for its value in joules, I found this website with the value of Rydberg constant $= 2.18times10^-18 textJ$.
How can Rydberg constant be written in joules?
energy atoms units
$endgroup$
add a comment |
$begingroup$
In my textbook (Chemistry Part - I for Class XI published by NCERT), there is an equation for the energy of an electron in an energy state: $$E_n = -R_mathrm Hleft(frac1n^2right)$$ and there is a paragraph below it with the following text:
where $R_mathrm H$ is called Rydberg constant and its value is $2.18times10^-18 textJ$.
There is another section with the expression for the wavenumber ($overlinenu$):
$$overlinenu=109,677 left(frac1n_1^2 - frac1n_2^2right) textcm^-1$$
with a paragraph with the following text:
The value $109,677 spacetextcm^-1$ is called the Rydberg constant for hydrogen.
I checked online and found that in most (all) websites (incl. Wikipedia), the value of Rydberg constant is $109,677 spacetextcm^-1$. But when I searched for its value in joules, I found this website with the value of Rydberg constant $= 2.18times10^-18 textJ$.
How can Rydberg constant be written in joules?
energy atoms units
$endgroup$
5
$begingroup$
How can a price of a cheeseburger be written in ¥? Well, just like that. Rydberg constant is energy, and Joule is energy, so what's the problem?
$endgroup$
– Ivan Neretin
Jun 5 at 7:14
1
$begingroup$
Look at the two different equations. Consider the dimensions in each case, and why that means in one case the Rydberg constant must have dimensions of Energy, and in the other it must have dimensions of wave number. Now what relations do you know relating Energy and wave number?
$endgroup$
– Ian Bush
Jun 5 at 7:16
$begingroup$
Although wavenumbers are not strictly energy you will see from the value in joules that it is much more convenient to use wavenumbers. The conversion is $ 1 ,mathrmcm^-1equiv 1.986cdot 10^-23$ J.
$endgroup$
– porphyrin
Jun 5 at 7:18
add a comment |
$begingroup$
In my textbook (Chemistry Part - I for Class XI published by NCERT), there is an equation for the energy of an electron in an energy state: $$E_n = -R_mathrm Hleft(frac1n^2right)$$ and there is a paragraph below it with the following text:
where $R_mathrm H$ is called Rydberg constant and its value is $2.18times10^-18 textJ$.
There is another section with the expression for the wavenumber ($overlinenu$):
$$overlinenu=109,677 left(frac1n_1^2 - frac1n_2^2right) textcm^-1$$
with a paragraph with the following text:
The value $109,677 spacetextcm^-1$ is called the Rydberg constant for hydrogen.
I checked online and found that in most (all) websites (incl. Wikipedia), the value of Rydberg constant is $109,677 spacetextcm^-1$. But when I searched for its value in joules, I found this website with the value of Rydberg constant $= 2.18times10^-18 textJ$.
How can Rydberg constant be written in joules?
energy atoms units
$endgroup$
In my textbook (Chemistry Part - I for Class XI published by NCERT), there is an equation for the energy of an electron in an energy state: $$E_n = -R_mathrm Hleft(frac1n^2right)$$ and there is a paragraph below it with the following text:
where $R_mathrm H$ is called Rydberg constant and its value is $2.18times10^-18 textJ$.
There is another section with the expression for the wavenumber ($overlinenu$):
$$overlinenu=109,677 left(frac1n_1^2 - frac1n_2^2right) textcm^-1$$
with a paragraph with the following text:
The value $109,677 spacetextcm^-1$ is called the Rydberg constant for hydrogen.
I checked online and found that in most (all) websites (incl. Wikipedia), the value of Rydberg constant is $109,677 spacetextcm^-1$. But when I searched for its value in joules, I found this website with the value of Rydberg constant $= 2.18times10^-18 textJ$.
How can Rydberg constant be written in joules?
energy atoms units
energy atoms units
edited Jun 5 at 17:38
Loong♦
35.2k888190
35.2k888190
asked Jun 5 at 6:49
Aditya SinghAditya Singh
536
536
5
$begingroup$
How can a price of a cheeseburger be written in ¥? Well, just like that. Rydberg constant is energy, and Joule is energy, so what's the problem?
$endgroup$
– Ivan Neretin
Jun 5 at 7:14
1
$begingroup$
Look at the two different equations. Consider the dimensions in each case, and why that means in one case the Rydberg constant must have dimensions of Energy, and in the other it must have dimensions of wave number. Now what relations do you know relating Energy and wave number?
$endgroup$
– Ian Bush
Jun 5 at 7:16
$begingroup$
Although wavenumbers are not strictly energy you will see from the value in joules that it is much more convenient to use wavenumbers. The conversion is $ 1 ,mathrmcm^-1equiv 1.986cdot 10^-23$ J.
$endgroup$
– porphyrin
Jun 5 at 7:18
add a comment |
5
$begingroup$
How can a price of a cheeseburger be written in ¥? Well, just like that. Rydberg constant is energy, and Joule is energy, so what's the problem?
$endgroup$
– Ivan Neretin
Jun 5 at 7:14
1
$begingroup$
Look at the two different equations. Consider the dimensions in each case, and why that means in one case the Rydberg constant must have dimensions of Energy, and in the other it must have dimensions of wave number. Now what relations do you know relating Energy and wave number?
$endgroup$
– Ian Bush
Jun 5 at 7:16
$begingroup$
Although wavenumbers are not strictly energy you will see from the value in joules that it is much more convenient to use wavenumbers. The conversion is $ 1 ,mathrmcm^-1equiv 1.986cdot 10^-23$ J.
$endgroup$
– porphyrin
Jun 5 at 7:18
5
5
$begingroup$
How can a price of a cheeseburger be written in ¥? Well, just like that. Rydberg constant is energy, and Joule is energy, so what's the problem?
$endgroup$
– Ivan Neretin
Jun 5 at 7:14
$begingroup$
How can a price of a cheeseburger be written in ¥? Well, just like that. Rydberg constant is energy, and Joule is energy, so what's the problem?
$endgroup$
– Ivan Neretin
Jun 5 at 7:14
1
1
$begingroup$
Look at the two different equations. Consider the dimensions in each case, and why that means in one case the Rydberg constant must have dimensions of Energy, and in the other it must have dimensions of wave number. Now what relations do you know relating Energy and wave number?
$endgroup$
– Ian Bush
Jun 5 at 7:16
$begingroup$
Look at the two different equations. Consider the dimensions in each case, and why that means in one case the Rydberg constant must have dimensions of Energy, and in the other it must have dimensions of wave number. Now what relations do you know relating Energy and wave number?
$endgroup$
– Ian Bush
Jun 5 at 7:16
$begingroup$
Although wavenumbers are not strictly energy you will see from the value in joules that it is much more convenient to use wavenumbers. The conversion is $ 1 ,mathrmcm^-1equiv 1.986cdot 10^-23$ J.
$endgroup$
– porphyrin
Jun 5 at 7:18
$begingroup$
Although wavenumbers are not strictly energy you will see from the value in joules that it is much more convenient to use wavenumbers. The conversion is $ 1 ,mathrmcm^-1equiv 1.986cdot 10^-23$ J.
$endgroup$
– porphyrin
Jun 5 at 7:18
add a comment |
3 Answers
3
active
oldest
votes
$begingroup$
Authors may be sloppy about notation in this matter. I recommend considering $R_ceH approx pu10973 cm-1$ and $Ry approx pu2.18e-18 J$, noting $Ry = hc cdot R_ceH$. Units of wavenumbers $(pucm-1)$ and energy are often considered interchangeable in practice because they are proportional to each other by the constant value $hc$.
In my notes, I would always be sure to write $R_ceH$ or $Ry$ to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)
Note also that there is a unit of energy known as a Rydberg, with $pu1 Ry = Ry = hc cdot R_ceH$.
$endgroup$
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
add a comment |
$begingroup$
Rydberg constant $R_∞$ is usually given in reciprocal length units historically and because it's determined from hydrogen and deuterium transition frequencies [1].
Current value (in $pum-1$) is listed at NIST [2] website (accessed 2019-06-05):
$$R_∞ = pu10973731.568160(21) m-1$$
Since it's an energy unit, one can convert it to SI rather trivially via multiplying the value in reciprocal length units by $hc$ ($h$ is the Planck constant; $c$ is the speed of light in vacuum):
$$E = hν = frachcλ quadtextorquad R_∞[puJ] = hccdot R_∞[pum-1]$$
resulting in the following value:
$$R_∞ = pu2.1798723611035(42)e-18 J$$
References
- Mohr, P. J.; Newell, D. B.; Taylor, B. N. CODATA Recommended Values of the Fundamental Physical Constants: 2014. Reviews of Modern Physics 2016, 88 (3). https://doi.org/10.1103/RevModPhys.88.035009.
- Tiesinga E.; Mohr P. J.; Newell D. B.; Taylor, B. N. "The 2018 CODATA Recommended Values of the Fundamental Physical Constants" (Web Version 8.0). Database developed by J. Baker, M. Douma, and S. Kotochigova. Available at http://physics.nist.gov/constants, National Institute of Standards and Technology, Gaithersburg, MD 20899. 2019.
$endgroup$
add a comment |
$begingroup$
In spectroscopy and related fields it is common to measure energy levels in units of reciprocal centimeters (e.g., IR and Ramon spectroscopy). Strictly speaking, these units ($pucm^−1$) are not energy units, but units proportional to energies, with $hc$ being the proportionality constant (Wikipedia). In general, $hc$ can be attributed to the value $pu1.986times 10^-23 Jcm$. Hence:
$$R_∞ = pu109677 cm^−1 $$
$$R_y= pu109677 cm^−1 times hc = pu109677 cm^−1 times pu1.986times 10^-23 Jcm = pu2.178times 10^-18 J $$
$endgroup$
add a comment |
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3 Answers
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active
oldest
votes
3 Answers
3
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
Authors may be sloppy about notation in this matter. I recommend considering $R_ceH approx pu10973 cm-1$ and $Ry approx pu2.18e-18 J$, noting $Ry = hc cdot R_ceH$. Units of wavenumbers $(pucm-1)$ and energy are often considered interchangeable in practice because they are proportional to each other by the constant value $hc$.
In my notes, I would always be sure to write $R_ceH$ or $Ry$ to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)
Note also that there is a unit of energy known as a Rydberg, with $pu1 Ry = Ry = hc cdot R_ceH$.
$endgroup$
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
add a comment |
$begingroup$
Authors may be sloppy about notation in this matter. I recommend considering $R_ceH approx pu10973 cm-1$ and $Ry approx pu2.18e-18 J$, noting $Ry = hc cdot R_ceH$. Units of wavenumbers $(pucm-1)$ and energy are often considered interchangeable in practice because they are proportional to each other by the constant value $hc$.
In my notes, I would always be sure to write $R_ceH$ or $Ry$ to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)
Note also that there is a unit of energy known as a Rydberg, with $pu1 Ry = Ry = hc cdot R_ceH$.
$endgroup$
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
add a comment |
$begingroup$
Authors may be sloppy about notation in this matter. I recommend considering $R_ceH approx pu10973 cm-1$ and $Ry approx pu2.18e-18 J$, noting $Ry = hc cdot R_ceH$. Units of wavenumbers $(pucm-1)$ and energy are often considered interchangeable in practice because they are proportional to each other by the constant value $hc$.
In my notes, I would always be sure to write $R_ceH$ or $Ry$ to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)
Note also that there is a unit of energy known as a Rydberg, with $pu1 Ry = Ry = hc cdot R_ceH$.
$endgroup$
Authors may be sloppy about notation in this matter. I recommend considering $R_ceH approx pu10973 cm-1$ and $Ry approx pu2.18e-18 J$, noting $Ry = hc cdot R_ceH$. Units of wavenumbers $(pucm-1)$ and energy are often considered interchangeable in practice because they are proportional to each other by the constant value $hc$.
In my notes, I would always be sure to write $R_ceH$ or $Ry$ to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)
Note also that there is a unit of energy known as a Rydberg, with $pu1 Ry = Ry = hc cdot R_ceH$.
edited Jun 5 at 7:22
andselisk♦
21.4k775143
21.4k775143
answered Jun 5 at 7:17
electronpusherelectronpusher
1,921511
1,921511
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
add a comment |
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
$begingroup$
My notation would have called for your Ry to be R subscript y. Assuming I get my mathjax right it would look like $ R_y $. This was clearly distinct from $ Ry $ even in my bad writing because the joint of the y was below the line.
$endgroup$
– Joshua
Jun 5 at 17:38
add a comment |
$begingroup$
Rydberg constant $R_∞$ is usually given in reciprocal length units historically and because it's determined from hydrogen and deuterium transition frequencies [1].
Current value (in $pum-1$) is listed at NIST [2] website (accessed 2019-06-05):
$$R_∞ = pu10973731.568160(21) m-1$$
Since it's an energy unit, one can convert it to SI rather trivially via multiplying the value in reciprocal length units by $hc$ ($h$ is the Planck constant; $c$ is the speed of light in vacuum):
$$E = hν = frachcλ quadtextorquad R_∞[puJ] = hccdot R_∞[pum-1]$$
resulting in the following value:
$$R_∞ = pu2.1798723611035(42)e-18 J$$
References
- Mohr, P. J.; Newell, D. B.; Taylor, B. N. CODATA Recommended Values of the Fundamental Physical Constants: 2014. Reviews of Modern Physics 2016, 88 (3). https://doi.org/10.1103/RevModPhys.88.035009.
- Tiesinga E.; Mohr P. J.; Newell D. B.; Taylor, B. N. "The 2018 CODATA Recommended Values of the Fundamental Physical Constants" (Web Version 8.0). Database developed by J. Baker, M. Douma, and S. Kotochigova. Available at http://physics.nist.gov/constants, National Institute of Standards and Technology, Gaithersburg, MD 20899. 2019.
$endgroup$
add a comment |
$begingroup$
Rydberg constant $R_∞$ is usually given in reciprocal length units historically and because it's determined from hydrogen and deuterium transition frequencies [1].
Current value (in $pum-1$) is listed at NIST [2] website (accessed 2019-06-05):
$$R_∞ = pu10973731.568160(21) m-1$$
Since it's an energy unit, one can convert it to SI rather trivially via multiplying the value in reciprocal length units by $hc$ ($h$ is the Planck constant; $c$ is the speed of light in vacuum):
$$E = hν = frachcλ quadtextorquad R_∞[puJ] = hccdot R_∞[pum-1]$$
resulting in the following value:
$$R_∞ = pu2.1798723611035(42)e-18 J$$
References
- Mohr, P. J.; Newell, D. B.; Taylor, B. N. CODATA Recommended Values of the Fundamental Physical Constants: 2014. Reviews of Modern Physics 2016, 88 (3). https://doi.org/10.1103/RevModPhys.88.035009.
- Tiesinga E.; Mohr P. J.; Newell D. B.; Taylor, B. N. "The 2018 CODATA Recommended Values of the Fundamental Physical Constants" (Web Version 8.0). Database developed by J. Baker, M. Douma, and S. Kotochigova. Available at http://physics.nist.gov/constants, National Institute of Standards and Technology, Gaithersburg, MD 20899. 2019.
$endgroup$
add a comment |
$begingroup$
Rydberg constant $R_∞$ is usually given in reciprocal length units historically and because it's determined from hydrogen and deuterium transition frequencies [1].
Current value (in $pum-1$) is listed at NIST [2] website (accessed 2019-06-05):
$$R_∞ = pu10973731.568160(21) m-1$$
Since it's an energy unit, one can convert it to SI rather trivially via multiplying the value in reciprocal length units by $hc$ ($h$ is the Planck constant; $c$ is the speed of light in vacuum):
$$E = hν = frachcλ quadtextorquad R_∞[puJ] = hccdot R_∞[pum-1]$$
resulting in the following value:
$$R_∞ = pu2.1798723611035(42)e-18 J$$
References
- Mohr, P. J.; Newell, D. B.; Taylor, B. N. CODATA Recommended Values of the Fundamental Physical Constants: 2014. Reviews of Modern Physics 2016, 88 (3). https://doi.org/10.1103/RevModPhys.88.035009.
- Tiesinga E.; Mohr P. J.; Newell D. B.; Taylor, B. N. "The 2018 CODATA Recommended Values of the Fundamental Physical Constants" (Web Version 8.0). Database developed by J. Baker, M. Douma, and S. Kotochigova. Available at http://physics.nist.gov/constants, National Institute of Standards and Technology, Gaithersburg, MD 20899. 2019.
$endgroup$
Rydberg constant $R_∞$ is usually given in reciprocal length units historically and because it's determined from hydrogen and deuterium transition frequencies [1].
Current value (in $pum-1$) is listed at NIST [2] website (accessed 2019-06-05):
$$R_∞ = pu10973731.568160(21) m-1$$
Since it's an energy unit, one can convert it to SI rather trivially via multiplying the value in reciprocal length units by $hc$ ($h$ is the Planck constant; $c$ is the speed of light in vacuum):
$$E = hν = frachcλ quadtextorquad R_∞[puJ] = hccdot R_∞[pum-1]$$
resulting in the following value:
$$R_∞ = pu2.1798723611035(42)e-18 J$$
References
- Mohr, P. J.; Newell, D. B.; Taylor, B. N. CODATA Recommended Values of the Fundamental Physical Constants: 2014. Reviews of Modern Physics 2016, 88 (3). https://doi.org/10.1103/RevModPhys.88.035009.
- Tiesinga E.; Mohr P. J.; Newell D. B.; Taylor, B. N. "The 2018 CODATA Recommended Values of the Fundamental Physical Constants" (Web Version 8.0). Database developed by J. Baker, M. Douma, and S. Kotochigova. Available at http://physics.nist.gov/constants, National Institute of Standards and Technology, Gaithersburg, MD 20899. 2019.
answered Jun 5 at 7:16
andselisk♦andselisk
21.4k775143
21.4k775143
add a comment |
add a comment |
$begingroup$
In spectroscopy and related fields it is common to measure energy levels in units of reciprocal centimeters (e.g., IR and Ramon spectroscopy). Strictly speaking, these units ($pucm^−1$) are not energy units, but units proportional to energies, with $hc$ being the proportionality constant (Wikipedia). In general, $hc$ can be attributed to the value $pu1.986times 10^-23 Jcm$. Hence:
$$R_∞ = pu109677 cm^−1 $$
$$R_y= pu109677 cm^−1 times hc = pu109677 cm^−1 times pu1.986times 10^-23 Jcm = pu2.178times 10^-18 J $$
$endgroup$
add a comment |
$begingroup$
In spectroscopy and related fields it is common to measure energy levels in units of reciprocal centimeters (e.g., IR and Ramon spectroscopy). Strictly speaking, these units ($pucm^−1$) are not energy units, but units proportional to energies, with $hc$ being the proportionality constant (Wikipedia). In general, $hc$ can be attributed to the value $pu1.986times 10^-23 Jcm$. Hence:
$$R_∞ = pu109677 cm^−1 $$
$$R_y= pu109677 cm^−1 times hc = pu109677 cm^−1 times pu1.986times 10^-23 Jcm = pu2.178times 10^-18 J $$
$endgroup$
add a comment |
$begingroup$
In spectroscopy and related fields it is common to measure energy levels in units of reciprocal centimeters (e.g., IR and Ramon spectroscopy). Strictly speaking, these units ($pucm^−1$) are not energy units, but units proportional to energies, with $hc$ being the proportionality constant (Wikipedia). In general, $hc$ can be attributed to the value $pu1.986times 10^-23 Jcm$. Hence:
$$R_∞ = pu109677 cm^−1 $$
$$R_y= pu109677 cm^−1 times hc = pu109677 cm^−1 times pu1.986times 10^-23 Jcm = pu2.178times 10^-18 J $$
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In spectroscopy and related fields it is common to measure energy levels in units of reciprocal centimeters (e.g., IR and Ramon spectroscopy). Strictly speaking, these units ($pucm^−1$) are not energy units, but units proportional to energies, with $hc$ being the proportionality constant (Wikipedia). In general, $hc$ can be attributed to the value $pu1.986times 10^-23 Jcm$. Hence:
$$R_∞ = pu109677 cm^−1 $$
$$R_y= pu109677 cm^−1 times hc = pu109677 cm^−1 times pu1.986times 10^-23 Jcm = pu2.178times 10^-18 J $$
edited Jun 5 at 17:59
Karsten Theis
7,2781051
7,2781051
answered Jun 5 at 17:32
Mathew MahindaratneMathew Mahindaratne
9,32611133
9,32611133
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5
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How can a price of a cheeseburger be written in ¥? Well, just like that. Rydberg constant is energy, and Joule is energy, so what's the problem?
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– Ivan Neretin
Jun 5 at 7:14
1
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Look at the two different equations. Consider the dimensions in each case, and why that means in one case the Rydberg constant must have dimensions of Energy, and in the other it must have dimensions of wave number. Now what relations do you know relating Energy and wave number?
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– Ian Bush
Jun 5 at 7:16
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Although wavenumbers are not strictly energy you will see from the value in joules that it is much more convenient to use wavenumbers. The conversion is $ 1 ,mathrmcm^-1equiv 1.986cdot 10^-23$ J.
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– porphyrin
Jun 5 at 7:18